Around 30 million people in Europe live in mountain valleys. A large part of this population is more affected by air pollution than previously assumed. This is the conclusion of a Slovenian-German research team from measurements in the Northern Dinaric Alps. Due to temperature inversions in winter, pollutants are trapped in the valleys to such an extent that soot and fine dust could reach alarming levels even in small villages, as they otherwise occur mainly in the centres of congested metropolises, write researchers from the Universities of Ljubljana, Molise and Nova Gorica and the Leibniz Institute for Tropospheric Research (TROPOS) in the scientific journal Atmospheric Chemistry and Physics (ACP). With mobile measurements using an instrumented backpack by TROPOS, it had become possible to examine the pollutant distribution in more detail.
Wood combustion is responsible for more than half of the small particulate matter (PM2.5) in Europe, which is dangerous to health. According to the European Environment Agency (EEA), wood combustion is now the largest source of this pollutant. The promotion of wood as a “carbon dioxide-neutral” fuel, the rising costs of fossil fuels and several financial crises have led to significantly increasing use of wood as an alternative source. People are more likely to burn wood for household heating in small heating systems.
Air quality studies have so far mostly focused on cities. However, in the EU, the UK and the four EFTA countries Iceland, Liechtenstein, Norway and Switzerland, over a quarter of the population live in rural areas. To study the impact of wood burning on the air quality in such villages, the researchers took a closer look at a karst hollow in Slovenia. The hollow in the municipality of Loški Potok around the village of Retje is representative of many mountainous and hilly rural areas in Central and South-Eastern Europe with wood heating systems. The study area is located in a shallow karst depression with a topography that favors the formation of temperature inversions and cold air pools typical in many valleys and relief depressions in winter. In addition to two fixed measuring stations at the bottom of the hollow in the village and on a hill, mobile measurements with instruments aboard a backpack, in particular, provided crucial details on the distribution of air pollutants in space. With this backpack, the team walked the six-kilometre route through the valley three times a day in December 2017 and January 2018 — in the morning, at midday and in the evening. In 107 measurement tours, 642 kilometres were covered on foot.
In addition to particulate matter, the team also examined one of its components: black carbon — colloquially also simply called “soot.” . Black cabon is produced by incomplete combustion of carbon-containing materials such as fossil fuels or wood. Among other things, carcinogenic substances adhere to the tiny soot particles. Black carbon is, therefore, considered a highly problematic component of particulate matter in terms of health. While the fixed measuring stations provided hourly concentrations of black carbon (eBC) of 1 to 40 micrograms per cubic metre and particulate matter concentrations (PM10) of 10 to 205 micrograms per cubic metre, the mobile measurements provided black carbon and PM2.5, but with levels more representative of the actual concentrations many people in the hollow were exposed to. These high levels of pollutants can be attributed to one effect that frequently occurs in the mountains in winter which proved to be particularly problematic: in the morning, the sun warms the upper parts of the relief depression faster than the lower parts — due to the morning fog that forms in the relief depression sheltered from the wind and prevents warming near the ground. The resulting temperature inversion acts like a lid on a pot: the exhaust gases and particles cannot escape upwards and concentrate at the bottom. In this study, several temperature inversion events occurred, during which the pedestrian level pollutant concentrations of soot (eBC) reached an average of 4.5 micrograms per cubic metre and of fine particulate matter (PM2.5) 48 micrograms per cubic metre, which is comparable to the centres of large metropolises where there is heavy traffic. These values are much larger than the European Union’s annual limit (20 micrograms per cubic metre) and the World Health Organisation’s (WHO) recommendations for the daily limit (15 micrograms per cubic metre). As measured by the EU Air Quality Index for fine particulate matter (PM10 and PM2.5), air quality was very poor during such temperature inversions. Overall, air quality was only moderate during the entire study period (December and January).
“During temperature inversions, pollutant levels in the hollow were highest in the early evening, reaching up to 22 micrograms per cubic metre for black carbon and 560 micrograms per cubic metre for particulate matter. This is the result of domestic wood burning, which increases when people come home after work, and the stable air layer at the bottom of the hollow. However, with some wind, both black carbon and particulate matter levels in the basin dropped to less than 1 and 12 micrograms per cubic metre, respectively, which is about four times lower than during a temperature inversion and in line with European regional background levels,” reports Dr. Kristina Glojek who studied for her PhD at the University of Ljubljana. During morning and afternoon temperature inversions, in the village of Retje, people living on the lower part of the south-facing slopes were most exposed to the high concentrations of particulate matter, while in the early evening hours, when the inversion is limited to the bottom of the hollow, people there breathe in the highest levels of pollutants.
Such weather conditions are typical for hilly and mountainous regions. During the study, temperature inversions occurred on more than 70 per cent of all winter nights and mornings. “These very stable conditions prevent effective mixing of the air in the relief depression, which leads to increased pollutant levels. Therefore, during temperature inversions, particulate matter concentrations in the sink rise to levels comparable to those in larger European city centres and above the EU daily limit value (PM10 = 50 micrograms per cubic metre) as well as above the annual limit value and the WHO daily guideline values (PM2.5 = 20 and 15 micrograms per cubic metre, respectively),” emphasises Prof. Mira Pöhlker from TROPOS.
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